ChemicalBook > CAS DataBase List > 4-Chlorophenylboronic acid
4-Chlorophenylboronic acid
- Product Name
- 4-Chlorophenylboronic acid
- CAS No.
- 1679-18-1
- Chemical Name
- 4-Chlorophenylboronic acid
- Synonyms
- 4-CHLOROBENZENEBORONIC ACID;AC 34441;NSC 25408;WLN: QBQR DG;AKOS BRN-0011;RARECHEM AH PB 0178;orobenzeneboronic Acid;p-chlorophenylboronic aci;4-Chlorophenylbronic Acid;The effects of boric acid
- CBNumber
- CB0307561
- Molecular Formula
- C6H6BClO2
- Formula Weight
- 156.37
- MOL File
- 1679-18-1.mol
More
Less
4-Chlorophenylboronic acid Property
- Melting point:
- 284-289 °C(lit.)
- Boiling point:
- 295.4±42.0 °C(Predicted)
- Density
- 1.32±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- DMSO
- pka
- 8.39±0.10(Predicted)
- form
- Crystalline Powder
- color
- Off-white to beige
- Water Solubility
- 2.5 g/100 mL
- BRN
- 2936346
- InChI
- InChI=1S/C6H6BClO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
- InChIKey
- CAYQIZIAYYNFCS-UHFFFAOYSA-N
- SMILES
- B(C1=CC=C(Cl)C=C1)(O)O
- CAS DataBase Reference
- 1679-18-1(CAS DataBase Reference)
More
Less
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 20/21/22-36/37/38
- Safety Statements
- 36-37/39-26
- WGK Germany
- 3
- RTECS
- CY8950000
- TSCA
- No
- HazardClass
- IRRITANT
- HS Code
- 29319090
More
Less
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 417548
- Product name
- 4-Chlorophenylboronic acid
- Purity
- 95%
- Packaging
- 1g
- Price
- $21.84
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 417548
- Product name
- 4-Chlorophenylboronic acid
- Purity
- 95%
- Packaging
- 10g
- Price
- $119
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C1473
- Product name
- 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5g
- Price
- $49
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C1473
- Product name
- 4-Chlorophenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 25g
- Price
- $141
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A15657
- Product name
- 4-Chlorobenzeneboronic acid, 98+%
- Packaging
- 1g
- Price
- $19.65
- Updated
- 2024/03/01
More
Less
4-Chlorophenylboronic acid Chemical Properties,Usage,Production
Chemical Properties
off-white to beige crystalline powder
Chemical Properties
4-Chlorophenylboronic acid is white or off-white crystalline powder. It has certain solubility in water and is soluble in strong polar organic solvents such as dimethyl sulfoxide, but insoluble in ether solvents. It has similar chemical properties to phenylboronic acid.
Uses
4-Chlorobenzeneboronic Acid is used as a catalyst for the preparation of 4-hydroxycoumarin derivatives which display antitrypanosomal and antioxidant properties. It is also used as a catalyst for the asymmetric borane reduction of electron-deficient ketones.
Uses
4-Chlorophenylboronic acid can be used as a reactant in:
- Palladium-catalyzed direct arylation.
- Cyclopalladation.
- Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation.
- Copper-mediated ligandless aerobic fluoroalkylation.
- Pd-catalyzed arylative cyclization.
- Ruthenium catalyzed direct arylation.
- Ligand-free copper-catalyzed coupling reactions.
- Regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions.
It can also be used to prepare:
- Substituted diarylmethylidenefluorenes via Suzuki coupling reaction.
- Baclofen lactam by Suzuki coupling of a pyrrolinyl tosylate, followed by hydrogenation reaction.
- Palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts.
- Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.
4-Chlorophenylboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
4-Chlorophenylboronic acid Suppliers
- Tel
- +1-510-219-6317
- Fax
- +1-650-486-1361
- sales@hbcchem.com
- Country
- United States
- ProdList
- 10658
- Advantage
- 60
- Tel
- 732-484-9848
- Fax
- 888-484-5008
- sales@chemscene.com
- Country
- United States
- ProdList
- 3986
- Advantage
- 60
- Tel
- +1-5166625404
- Fax
- 1-516-927-0118
- Info@alfa-chemistry.com
- Country
- United States
- ProdList
- 21317
- Advantage
- 58
- Tel
- (+1)-858-699-3322
- Fax
- (+1)-858-876-1948
- info@accelachem.com
- Country
- United States
- ProdList
- 19965
- Advantage
- 58
- Tel
- 8485655694
- sales@alchempharmtech.com
- Country
- United States
- ProdList
- 63711
- Advantage
- 58
- Tel
- +1-833-552-7181
- sales@aladdinsci.com
- Country
- United States
- ProdList
- 57511
- Advantage
- 58
- Tel
- +1-817863-6948 +1-（817）863-6948
- sales@aceschem.com
- Country
- United States
- ProdList
- 19639
- Advantage
- 58
More
Less
View Lastest Price from 4-Chlorophenylboronic acid manufacturers
Hebei Saisier Technology Co., LTD
- Product
- 4-Chlorophenylboronic acid 1679-18-1
- Price
- US $6.00/KG
- Min. Order
- 1KG
- Purity
- More than 99%
- Supply Ability
- 2000KG/MONTH
- Release date
- 2024-04-24
Henan Fengda Chemical Co., Ltd
- Product
- 4-Chlorophenylboronic acid 1679-18-1
- Price
- US $34.00-1.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
Hebei Xinsheng New Material Technology Co., LTD.
- Product
- 4-Chlorophenylboronic acid 1679-18-1
- Price
- US $35.00-25.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 Ton
- Release date
- 2023-10-31
1679-18-1, 4-Chlorophenylboronic acidRelated Search:
4-Chlorobenzoic acid
4-Chlorophenoxyacetic acid sodium salt
HexanitrodiphenylaMine
Chlorphenamine maleate
1,2,4-Trichlorobenzene
4-Fluorobenzeneboronic acid
Phenylboronic acid
4-Chlorobenzaldehyde
Zinc borate
4-Chloronitrobenzene
4-Chloro-3-fluorobenzeneboronic acid
(4-CHLORO-2-ETHOXYPHENYL)BORONIC ACID
2,4-Dichlorophenylboronic acid
(3-AMINO-4-CHLOROPHENYL)BORONIC ACID HYDROCHLORIDE
4-Chloro-2-methoxyphenylboronic acid
4-CHLORO-2-METHYLPHENYLBORONIC ACID
4-Chloro-3-(trifluoromethyl)phenylboronic acid
2,4,6-Trichlorophenylboronic acid